The 'new' Alfa 3.2 is nothing like a Holden 3.8 V6. Only the bottom end is out of the Holden factory AFAIK, and heads/valves, intake plenum, ECU/mapping are not Holden/GM. So the engine is far more Alfa than Holden.
Alfa 3.2 bore x stroke: 85.6 x 90mm
Holden 3.0 bore x stroke: 89 x 83mm
Holden 3.6 bore x stroke: 94 x 85.6mm
Crankshafts may very well be totally different too.
LS engines are dinosaurs out of the US, and not produced by Holden in Australia.
Holden's 3.0 V6 direct injection engine is good for 190kW/290Nm, so that's not bad. 3.6 V6 direct injection produces 210kW/350Nm, which would be handy in the Alfa. But the engines are so different in shape that it probably won't drop into an Alfa chassis.
As with any engine mod like proposed, it would be expensive but do-able. Bore it out, new cylinder sleeves, new pistons, then at least an ECU upgrade to suit. For best results, you might need uprated injectors, fuel pump/pressure, head work, bigger throttle body, etc. No idea exactly what upgrades would help cos I've not researched it.
But maybe a 'stroker' crankshaft could be the goer. That way you don't touch the heads, just increase the stroke and leave the bore the same. (You might still need mods to prevent the pistons hitting the valves/heads)
I suppose you want to find a reputable local engine tuner who can perform the mods. Maybe even speak with Autodelta because they may have done the research compared with their supercharger option.
