In urban traffic, the tyre size doesn't make a lot of difference in fuel consumption. What makes the car consume most is its weight in combination with the engine and drive train. You got a
heavy car with a
big engine that is optimized for long distance travels (diesel). But it is not good for urban short distance, stop and go, etc.
So, for better fuel consumption on long distance travels, you could choose a smaller rim size (16" or 17") with the right tyre size (as approved by Alfa and MOT). Smaller rims are lighter. You can inflate the tyres with 0,2-0,3 bars of additional pressure. Some (premium) manufacturers produce special "eco" tyres that are optimized for lower fuel consumption. But getting a set of rims with new, premium quality tyres will cost you more than you will save in fuel…
Best "objective" idea would be to get a vehicle that is better suited for your needs, like a smaller car with a small engine, an electrical vehicle, or a scooter or a bike.
Or just pay the bills and enjoy your Alfa
