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There should be a mark on the front pulley to show alignment for number 1 on TDC.
Image from rebuild manual for 3.0 24V shows.
939806

I assume 2.5L in the 156 is the same.
 

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The images I have used are taken from the Alfa Romeo GTV workshop manuals. It covers 12V and 24V Busso and TS engines. There is also a supplement for Phase 3 3.2 technical data. The 3.2 and 3.0 24V engines are the same from the workshop manual information information perspective.
 

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I would just go with a replacement engine. if you want a real treat then get a 3.0 V6 from a GTV or 166 - not much more in terms of cost and a lot better to drive. It is a shame your cambelt snapped but it could be worth the effort to replace with a 3.0 V6.
 
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