Some stuff about tyre pressures is below:
..but the most important thing is to use all the track and be as smooth as possible.
Have an absolutely clear plan of what part of the apex you are aiming for and the flow of the line you see through the corner.
Make sure to attack the corner entry as slow as is neccessary to make that apex you have picked. Slow in-fast out sounds simple right?

Male testosterone normally makes us go really-fast-in, and pathetic scrubbing out - it takes quite a few laps to get that out of your system normally!
When you start track days everybody enters the corners way to quickly (you want to go fast right? wrong!

) on their first day, they miss the apex by miles and have to wait ages before the can apply full throttle out of the corner
The best tip I ever got, was that if you need to apply extra lock after the apex you are generally doing somehting wrong - likely trying to carry an unrealistic amount of speed but could be an error of line or balance. Generally the minute you make the apex you should be able to gradually let off lock as you apply extra throttle.
This tip will probably not make too much sense to you on your first day, but if you watch a video of what you are doing it is an easy thing to see if you are doing.
Pressures:
10% over normal pressure is a good start.
You may have to let some out once its warmed up - take the first session very handy since your tyres will get the pressure a little high near the end.
However it is much better to let some hot air out after your first session than put way less air in at the beginning and heat it up way more to get the same target HOT pressure..
With the former way the tyre temperature will be cooler for the same pressure (Charles law).
If you start with too little air your tyres will quickly heat up due to the extra movement of the tyre so you will reach your target pressure okay ..but with higher air temperatures.
With 225/45/17 I normally start at 2.5 or 2.6 bar cold and let it up to 2.8 or 2.9 bar hot (just after coming in from a session) .
You can monitor the pressure simply by checking the amount of wear over the sidewall line that marks the end of the area of the sidewall that was designed to be used for cornering.
If any wear shows over it then increase the pressure.
If the edge of the wear on the tyre is nowhere near the line that makrs the limit then you could reduce the pressure to gain traction (or drive faster!).
Have fun!