If it's only the valve, you're in luck, just a few quid, they can do that when you get the system serviced.
If your A/C system has been open to atmosphere for a while, though, you will really need to replace the receiver/dryer.
This is filled with a dessicant to remove any moisture from the refrigerant. Once the atmosphere has got to it, however, it will need replacing, adds another £40-60 to your bill...